Dynamic covalent single chain nanoparticles based on hetero Diels-Alder chemistry.
نویسندگان
چکیده
We introduce the fully reversible folding of single chain nanoparticles (SCNPs) based on covalent hetero Diels-Alder (HDA) chemistry. A cyclopentadiene (Cp)-protected cyanodithioester (CDTE) monomer is designed and copolymerized with methyl methacrylate (MMA) via RAFT polymerization. The polymer chains are folded and subsequently unfolded by exploiting the reversible nature of the HDA reaction.
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ورودعنوان ژورنال:
- Chemical communications
دوره 53 1 شماره
صفحات -
تاریخ انتشار 2016